PtCl2-Catalyzed Cycloisomerization of 1,8-Enynes: Synthesis of Tetrahydropyridine Species
Publication in refereed journal

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摘要The cycloisomerization of 1,8-enynes in the presence of platinum(II) chloride was developed to generate bicyclist's nitrogen-containing heterocycle species via 6-endo-dig cyclisation and [3,3]-sigmatropic rearrangement in acceptable to good yields. The related control experiments and preliminary mechanistic studies indicate a plausible mechanism involving 1,6-endo-dig aminoplatination of the alkyne and allylic [3,3]-sigmatropic rearrangement with total inversion of the allylic moiety.
出版社接受日期01.05.2019
著者Anvar Mirzaei, Xiao-Shui Peng, Henry N.C. Wong
期刊名稱Organic Letters
出版年份2019
月份5
卷號21
期次10
出版社American Chemical Society
出版地Columbus, Ohio
頁次3795 - 3798
國際標準期刊號1523-7060
電子國際標準期刊號1523-7052
語言美式英語
關鍵詞Cycloisomerization, 1,8-enyne, tetrahydropyridine, platinum(II) chloride

上次更新時間 2020-24-10 於 03:49