Synthetic Studies toward Lindenane-type Dimers via Diels-Alder Reaction
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AbstractLindenane-type dimers are natural sesquiterpenoids, mainly from Chloranthaceae, possessing an unique heptacyclic skeleton and diverse bioactivities. Inspection of their structures suggested the possibility of deploying an endo Diels-Alder reaction to construct the key cyclohexene ring. In this article we investigated the feasibility of Diels-Alder reactions between various dienes and dienophiles, leading ultimately to their applications to the realization of [4 + 2] lindenane dimers.
Acceptance Date05/10/2018
All Author(s) ListJian-Li Wu, Yin-Suo Lu, Henry N.C. Wong, Xiao-Shui Peng
Journal nameTetrahedron
Volume Number74
Issue Number47
PublisherElsevier Ltd.
Place of PublicationAmsterdam
Pages6749 - 6760
LanguagesEnglish-United States
KeywordsDiels-Alder, Lindenane, Sesquiterpenoid, Total synthesis

Last updated on 2020-23-11 at 01:53