Synthesis, Structure, and Reactivity of Carboranyl-Supported Germylenes: Approaching Germanones
Publication in refereed journal

香港中文大學研究人員
替代計量分析
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其它資訊
摘要Two iminocarboranyl germylenes, 1,2-[C(tBu)=N(Dipp)Ge(Cl)]-1,2-C2B10H10 (2) (Dipp = 2,6-iPr(2)C(6)H(3)) and [1-{C(tBu)=N(Dipp)}-1,2-C2B10H10](2)Ge (3), have been prepared and structurally characterized. The reaction of 2 with Me3NO or S-8 afforded the germanium oxygen- or sulfur-bridged dimer [1-{C(tBu)=N(Dipp)-1,2-C2B10H10}Ge(mu-O)(Cl)](2) (4) or [1-{C(tBu)=N(Dipp)-1,2-C2B10H10}Ge(mu-S)(Cl)](2) (5) containing a four-membered Ge2O2 or Ge2S2 ring, respectively. On the other hand, the reaction of 2 with K[CpFe(CO)(2)] led to the isolation of an iron-germylene compound featuring a Ge-Fe sigma bond, 1,2-{C(tBu)=N(Dipp)Ge[Fe(Cp)(CO)(2)]}-1,2-C2B10H10 (6). All new compounds were characterized by multiple NMR spectroscopic techniques and single-crystal X-ray analysis.
著者Wang H, Xie ZW
期刊名稱European Journal of Inorganic Chemistry
出版年份2017
月份10
日期25
期次38-39
頁次4430 - 4435
國際標準期刊號1434-1948
電子國際標準期刊號1099-0682
語言英式英語
關鍵詞Carboranes,Germanium,Germylenes,Germanones,Oxidation
Web of Science 學科類別Chemistry, Inorganic & Nuclear;Chemistry

上次更新時間 2020-30-11 於 02:00