Enantiomerically pure tetraphenylene-based homochiral macrocyclic tetramer and its recognition property towards C76 fullerene
Publication in refereed journal

替代計量分析
.

其它資訊
摘要The synthesis and characterisation of novel homochiral oligomacrocycle species composed of enantiomerically-pure tetraphenylene were described. Structural studies showed that the macrocyclic molecule possessed a helical chiral cavity, which exhibited unique and efficient recognition affinity towards fullerene C76 in toluene, as demonstrated by UV-vis titration experiments. The binding results were also interpreted through semi-empirical calculations.
著者Chun-Lin Deng, Xiao-Shui Peng, Henry N.C. Wong
期刊名稱Tetrahedron
出版年份2017
月份6
日期29
卷號73
期次26
出版社Elsevier Ltd.
出版地Amsterdam
頁次3606 - 3611
國際標準期刊號0040-4020
語言美式英語
關鍵詞Tetraphenylene, chirality, macrocycle, higher fullerene, host-guest chemistry, semi-empirical calculations.

上次更新時間 2020-25-10 於 02:47