Catalytic carbon-carbon sigma-bond hydrogenolysis
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AbstractCatalytic hydrogenolysis of carbon-carbon sigma bond in organic substrates represents an interesting, yet less common reduction methodology in chemical transformations. In the past few decades, there are impressive works aiming at mechanistic understanding via strategic reaction design. Efforts to expand synthetic usefulness have been observed. This digest summarizes the recent achievements in transition metal catalyzed reductive C-C sigma bond cleavage to give C-H bonds by hydrogenolysis. (C) 2016 Elsevier Ltd. All rights reserved.
All Author(s) ListTo CT, Chan KS
Journal nameTetrahedron Letters
Volume Number57
Issue Number42
Pages4664 - 4669
LanguagesEnglish-United Kingdom
KeywordsC-C sigma bond; Hydrogenolysis; Oxidative addition; Reductive cleavage
Web of Science Subject CategoriesChemistry; Chemistry, Organic

Last updated on 2021-16-09 at 01:47