Novel binuclear copper(I) complexes with unusual azide and thiocyanate bridges. Crystal structures of [Cu2(μ-Ph2Ppypz)2(μ-1,1-N 3)]-[ClO4]·Et2O and [Cu2(μ-Ph2Ppypz)2(μ-1,1-SCN)][ClO 4] [Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine]
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AbstractThe first binuclear copper(I) complex with a μ-1,1-N3 bridge, [Cu2(μ-Ph2Ppypz)2(μ-1,1-N 3)][ClO4]·Et2O and [Cu2(μ-Ph2-Ppypz)2(μ-1,1-SCN)][ClO 4][Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine], which exhibits an unusual thiocyanate (μ-1,1-SCN) bridge, have been synthesised and characterised.
All Author(s) ListKuang S.-M., Zhang Z.-Z., Wang Q.-G., Mak T.C.W.
Journal nameJournal of the Chemical Society, Dalton Transactions (1972-1999)
Year1997
Month12
Day7
Issue Number23
PublisherRoyal Society of Chemistry
Place of PublicationUnited Kingdom
Pages4477 - 4478
ISSN0300-9246
LanguagesEnglish-United Kingdom

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