α-naphthyl phenyl pinacols
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摘要Treatment of α-naphthyl phenyl ketone with Zn/acetic acid gives racemic α-naphthyl phenyl pinacol [1,2-di(1-naphthyl)-1,2-diphenylethane-1,2-diol], C34H26O2, but reaction with Mg/MgI2 gives a product which proves to be not a pinacol, but a tricyclic compound (with four chiral centers, formed by addition at the 2-position of one of the naphthalene groups), racemic 5-(1-naphthyl)-3,5-diphenyl-4-oxatricyclo[7.4.0.0 2,6]trideca-7,9,11,13-tetraen-3-ol, C34H26O2. The aromatic ring in this tricyclic compound is planar, but the other six-membered ring, and the five-membered furano ring, are non-planar. Bond lengths and angles in both molecules correspond to the molecular formulations. In both structures, the OH groups are involved in only weak intermolecular interactions.
著者Mak T.C.W., Patrick B.O., Rettig S.J., Scheffer J.R., Trotter J., Ukpabi P., Wu B.-M., Yee V.C.
期刊名稱Acta Crystallographica Section C: Crystal Structure Communications
出版年份1998
月份8
日期15
卷號54
期次8
出版社Blackwell Publishing Inc.
出版地United Kingdom
頁次1148 - 1151
國際標準期刊號0108-2701
電子國際標準期刊號1600-5759
語言英式英語