A polymeric cadmium (II) complex with an olefinic double-betaine containing metal centers in four different coordination environments, [{Cd3(L)3I2(H2O)6}] (CdI4)2n · nH2O (L = cis-(p-Me2N+C5H4N)2C 2(CO2
-)2)
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AbstractThe title complex contains five crystallographically independent cadmium(II) atoms in four different coordination environments, namely tetrahedral, distorted trigonal bipyramidal, octahedral and an irregular seven-coordinate geometry. The crystal structure exhibits a polymeric knotted double-chain comprising an alternate arrangement of 18- and 28-membered metallacyclic rings, with discrete [CdI4]2- anions packed inside channels in the intervening space.
All Author(s) ListWu D.-D., Mak T.C.W.
Journal nameInorganica Chimica Acta
Year1996
Month4
Day1
Volume Number245
Issue Number1
PublisherElsevier BV
Place of PublicationNetherlands
Pages123 - 128
ISSN0020-1693
eISSN1873-3255
LanguagesEnglish-United Kingdom
KeywordsBetaine complexes, Cadmium complexes, Crystal structures, Polymeric complexes

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