Silver(I) Cage and Infinite Chain Stabilized by Bowl-Shaped Resorcin[4]arene Tetraethynide Ligands
Publication in refereed journal

香港中文大學研究人員
替代計量分析
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其它資訊
摘要We present a new family of Ag(I) complexes bearing calixarene-based tetraethynide ligands, namely, [Ag-12(L1)(2)center dot(CH3CN)(4)center dot(NO3)(4)]center dot 2H(2)O (1), [Ag(4)L1(AgCF3CO2)(4)(CH3O14)] (2), [Ag4L2 center dot(AgCF3CO2)(4)]center dot H2O (3), and [Ag(4)L3 center dot(AgCF3CO2)(4)]center dot 0.75CH(3)COCH(3) (4), which were obtained from the reaction of newly synthesized tetraethynyl functionalized resorcin[4]arenes with silver(I) salts. Complex 1 features a 4/m assembly comprising a Agi, cage sandwiched by two bowl-shaped resorcin[4]arene tetraethynides, while 2-4 exhibit similar silver(I) chain structures each stabilized by an alternate attachment of bowl shaped resorcin[4]arene tetraethynide units. This work provides the successful example of the use of calixarene-based ligands for the construction of multinudear silver(I) ethynide supramolecular frameworks.
著者Han X, Jin SS, Ma JF, Yang J, Mak TCW
期刊名稱Crystal Growth and Design
出版年份2016
月份5
日期26
卷號16
期次7
出版社AMER CHEMICAL SOC
頁次3811 - 3817
國際標準期刊號1528-7483
電子國際標準期刊號1528-7505
語言英式英語
Web of Science 學科類別Chemistry, Multidisciplinary;Crystallography;Materials Science, Multidisciplinary;Chemistry;Crystallography;Materials Science

上次更新時間 2020-30-11 於 01:56