High-nuclearity silver(I) chalcogenide clusters: A novel class of supramolecular assembly
Publication in refereed journal

香港中文大學研究人員
替代計量分析
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摘要The high-nuclearity silver(I) clusters, a novel class of supramolecular assembly of silver(I) complexes, were usually prepared by incorporating silver ions with various ligands. Notably, a large number of argentophilic interactions exist in the high-nuclearity silver clusters. These interactions influence significantly a variety of structural and other physical characteristics. Thus, we will summarize the synthesis and structure of high-nuclearity silver(I) clusters with chalcogenide [E](2-) (E = S, Se and Te), chalcogenolate [RE](-) (E = S, Se and Te), dichalcogenophosphate [(RO)(2)PE2](-) (E = S and Se), and dichalcogenophosphonate [R(R'0)PS2](-) or [RP(O)S-2](2-). This results in deeper understanding of the relationship between synthesis conditions and the finally isolated products. The literature survey is up to December 2015 and the review represents the first article covering the span of various types of high-nuclearity Ag-E clusters and should contribute considerable value for future research. (C) 2016 Elsevier B.V. All rights reserved.
著者Xie YP, Jin JL, Duan GX, Lu X, Mak TCW
期刊名稱Coordination Chemistry Reviews
出版年份2017
月份1
日期15
卷號331
出版社ELSEVIER SCIENCE SA
頁次54 - 72
國際標準期刊號0010-8545
電子國際標準期刊號1873-3840
語言英式英語
關鍵詞Silver(I) clusters, Chalcogenide, Chalcogenolate, Dichalcogenophosphate, Dithiophosphonate
Web of Science 學科類別Chemistry, Inorganic & Nuclear;Chemistry

上次更新時間 2020-30-11 於 01:56