α-olefins as alkenylmetal equivalents in catalytic conjugate addition reactions
Publication in refereed journal

替代計量分析
.

其它資訊
摘要(Chemical Equation Presented) In the presence of a silyl triflate and an amine base, a nickel-phosphine complex catalyzes the direct conjugate addition of ethylene, α-olefins, and aryl alkenes to unsaturated aldehydes and ketones. The enolsilane products are isolated in good to very high yield, and in very high stereoselectivity for some cases. The alkene is a functional equivalent of an alkenylmetal reagent in the transformation. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
著者Ho C.-Y., Ohmiya H., Jamison T.F.
期刊名稱Angewandte Chemie International Edition
出版年份2008
月份2
日期22
卷號47
期次10
出版社John Wiley & Sons Ltd.
出版地United Kingdom
頁次1893 - 1895
國際標準期刊號1433-7851
電子國際標準期刊號1521-3773
語言英式英語
關鍵詞C-C coupling, Conjugate additions, Enolsilanes, Nickel, Olefins

上次更新時間 2021-11-01 於 01:59