Reduction of enedicarboxylate compounds with low valent titanium
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AbstractThe carbon—carbon double bonds of enedicarboxylate compounds can be reduced readily with TiCl4LiAlH4Et3N in THF. Other double bond of the enedicarboxylate does not react during the reduction process.

The carbon–carbon double bond of enedicarboxylate can be reduced by low valent titanium chemo-specifically in the presence of other isolated double bond. Stereoselectivity has also been observed for some examples.
All Author(s) ListHUNG CW, WONG HNC
Journal nameTetrahedron Letters
Volume Number28
Issue Number21
Pages2393 - 2396
LanguagesEnglish-United States

Last updated on 2020-02-08 at 00:37