Structures and chemotaxonomic significance of stemona alkaloids from stemona japonica
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AbstractA pair of new alkaloid stereo-isomers, stemocochinin (1) and isostemocochinin (2), was obtained from the roots of Stemona japonica Miq., along with seven known alkaloids, stemonamine (3), isostemonamine (4), maistemonine (5), isomaistemonine (6), croomine (7), stemonine (8), and protostemonine (9). The complete structure and stereochemistry of the pair of isomers were established by extensive analysis of the spectral data. Furthermore, our results indicated that S. japonica is chemically closer to S. sessilifolia than S. Tuberosa, which are consistent with our previous DNA study on Stemona species.
All Author(s) ListYi M., Xia X., Wu H.-Y., Tian H.-Y., Huang C., But P.P.-H., Shaw P.-C., Jiang R.-W.
Journal nameNatural Product Communications
Year2015
Month1
Day1
Volume Number10
Issue Number12
PublisherNatural Product Communications
Place of PublicationUnited States
Pages2097 - 2099
ISSN1934-578X
eISSN1555-9475
LanguagesEnglish-United Kingdom
KeywordsChemotaxonomic significance, DNA phylogenetics, Stemona alkaloid, Stemona japonica

Last updated on 2020-27-05 at 02:10