C60-catalyzed direct C-H arylation of benzene with aryl iodides in air
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AbstractC60 at 1 mol % loading catalyzed the direct C-H arylation of benzene with aryl iodides in air to yield biaryls. The in situ generation of electron-rich C60(OH)2-, from C60 and OH-, reduced the aryl iodides to aryl radicals for arylation of benzene. The large surface area and spherical shape of C60 facilitated this process.
All Author(s) ListKwok T.Y., Sonnenschein C., To C.T., Liu J., Chan K.S.
Journal nameTetrahedron
Detailed descriptionTo ORKTS: Christoph Sonnenschein was an exchange student
Jianwen Liu is a non-CU staff after graduation
Year2016
Month6
Day2
Volume Number72
Issue Number22
PublisherPergamon Press Ltd.
Place of PublicationUnited Kingdom
Pages2719 - 2724
ISSN1464-5416
LanguagesEnglish-United Kingdom
KeywordsBiaryl, C60 , Direct C-H arylation, Reduction

Last updated on 2020-22-10 at 02:30