Total Synthesis of (+/-)-Gracilioether F
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AbstractTotal synthesis of (+)-gracilioether F was achieved via a pivotal reductive cleavage of 1,2-dioxane from allenic ester in 11 steps. The key 1,2-dioxane species, derived from singlet oxygen and a diene, could be used as a common precursor for a stereocontrolled formation of the crucial 1,4-diol through a reductive cleavage.
All Author(s) ListShen XY, Peng XS, Wong HNC
Journal nameOrganic Letters
Detailed descriptionThe Erratum to this article has been published in Journal of Organic Letters 2016 18(5), 1032-1035 10.1021/acs.orglett.6b00161 - "The scheme in the abstract and table of contents graphic was incorrect. The structure of the intermediate shown (compound 14) was incorrect. The corrected scheme is shown below."
Volume Number18
Issue Number5
Pages1032 - 1035
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry, Organic;Chemistry

Last updated on 2021-14-09 at 00:48