Total Synthesis of (±)-Gracilioether F
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AbstractTotal synthesis of (±)-gracilioether F was achieved via a pivotal reductive cleavage of 1,2-dioxane from allenic ester in 11 steps. The key 1,2-dioxane species, derived from singlet oxygen and a diene, could be used as a common precursor for a stereocontrolled formation of the crucial 1,4-diol through a reductive cleavage.
All Author(s) ListShen X.-Y., Peng X.-S., Wong H.N.C.
Journal nameOrganic Letters
Volume Number18
Issue Number5
PublisherAmerican Chemical Society
Place of PublicationUnited States
Pages1032 - 1035
LanguagesEnglish-United Kingdom

Last updated on 2020-16-07 at 03:20