Base-Promoted, Aerobic, and Regioselective Carbon-Hydrogen Bond Activation of Thiophene with Group 9 Metalloporphyrins
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AbstractBase-promoted aerobic carbon hydrogen bond activation (CHA) of thiophene was achieved with high regioselectivity at the 2-position by group 9 metalloporphyrins in moderate to high yields. Mechanistic investigations suggest a homolytic aromatic substitution through M-II(ttp) (M = Rh, Ir) metalloradical addition, followed by beta-elimination of a metal hydride pathway.
All Author(s) ListYang W, Zhang HJ, Li LX, Tam CM, Feng SY, Wong KL, Lai WY, Ng SH, Chen C, Chan KS
Journal nameOrganometallics
Detailed descriptionTo ORKTS: Li Liuxiao is a CU graduate student but dropped out this summer. I cannot input her student no to input the data.
Volume Number35
Issue Number19
Pages3295 - 3300
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic

Last updated on 2021-17-09 at 01:35