Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene
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AbstractA highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.
All Author(s) ListDeng CL, Hau SCK, Peng XS, Wong HNC
Journal nameSYNLETT
Year2016
Month9
Day1
Volume Number27
Issue Number14
PublisherGEORG THIEME VERLAG KG
Pages2095 - 2100
ISSN0936-5214
eISSN1437-2096
LanguagesEnglish-United Kingdom
Keywordscation interactions; host-guest chemistry; macrocycle; nonplanar hydrocarbon; tetraphenylene
Web of Science Subject CategoriesChemistry; Chemistry, Organic

Last updated on 2020-12-07 at 04:41