Assembly of organosilver coordination frameworks with polycyclic benzenoid aromatic ethynide ligands
Publication in refereed journal

香港中文大學研究人員

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摘要In a series of nine silver(I) complexes synthesized with ethynyl-functionalized condensed-ring benzenoid aromatics, the terminal ethynide group is invariably inserted into an argentophilic Agn (n = 4-5) basket, leading to the generation of coordination chains or multinuclear metallocycles via silver-aromatic interaction and strong face-to-face aromatic pep stacking interaction. The coordination preferences of the ethynide ligand with respect to the size of the aromatic nucleus proved to be dominant factors in directing the construction of multi-dimensional organosilver(I) networks, which are consolidated by weak intermolecular interactions in supramolecular assembly. (C) 2015 Elsevier B.V. All rights reserved.
著者Hau SCK, Mak TCW
期刊名稱Journal of Organometallic Chemistry,Journal of Organometallic Chemistry
出版年份2015
月份9
日期1
卷號792
出版社ELSEVIER SCIENCE SA
頁次123 - 133
國際標準期刊號0022-328X
電子國際標準期刊號1872-8561
語言英式英語
關鍵詞Argentophilicity; Coordination framework; Organosilver complex; Polycyclic benzenoid aromatic ethynide
Web of Science 學科類別Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic

上次更新時間 2020-20-11 於 02:11