[3-N-2-o-C2B10H11][BF4]: a useful synthon for multiple cage boron functionalizations of o-carborane
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AbstractA simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N-2-o-C2B10H11][BF4] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C2B10H11 (X = OH, SCN, NH2, NO2, N-3, CF3, PO(C6H5)(2), etc). This reaction may serve as another efficient [F-18]-radiolabeling method of carborane clusters for positron emission tomography applications.
Acceptance Date07/06/2016
All Author(s) ListDa Zhao, Zuowei Xie
Journal nameChemical Science
Year2016
Month9
Day1
Volume Number7
Issue Number9
PublisherROYAL SOC CHEMISTRY
Pages5635 - 5639
ISSN2041-6520
eISSN2041-6539
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Multidisciplinary

Last updated on 2020-29-03 at 00:26