Phosphine-catalyzed cage carbon functionalization of o-carborane: facile synthesis of alkenylcarboranes
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AbstractA phosphine-catalyzed alkenylation reaction of o-carborane with electron-deficient alkynes at the C-H vertex of the o-carborane cage has been developed, which led to the preparation of a series of 1-alkenyl-o-carboranes inmoderate to very good yields with excellent regio- and stereoselectivity. This highly efficient and simple method represents the first example of organophosphine catalyzed C-H functionalization of o-carborane.
All Author(s) ListZheng FR, Leung TF, Chan KW, Sung HHY, Williams ID, Xie ZW, Jia GC
Journal nameChemical Communications
Year2016
Month1
Day1
Volume Number52
Issue Number71
PublisherROYAL SOC CHEMISTRY
Pages10767 - 10770
ISSN1359-7345
eISSN1364-548X
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Multidisciplinary

Last updated on 2020-28-10 at 02:06