Ethynide-stabilized high-nuclearity silver(I) sulfido molecular clusters assembled using organic sulfide precursors
Publication in refereed journal

香港中文大學研究人員

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摘要Inexpensive 1,1'-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver(I) sulfido molecular clusters [Ag9S6@Ag-36(C (CBu)-Bu-t)(32)(H2O)(2)] [Ag(imidazole)-(CH3OH)(H2O)](BF4) 2 center dot 8H(2)O center dot 2CH(3)OH (1) and [Ag120S24(PhC C)(52)-Cl-4(2-pyridone)(10)(H2O)(8)](H3O)(4)(SiF6)(8)(BF4)(4)center dot CH3OH center dot 22H(2)O (2), the latter being the largest isolated silver(I) ethynide cluster reported to date.
著者Chen ZY, Tam DYS, Mak TCW
期刊名稱Chemical Communications
出版年份2016
月份1
日期1
卷號52
期次36
出版社ROYAL SOC CHEMISTRY
頁次6119 - 6122
國際標準期刊號1359-7345
電子國際標準期刊號1364-548X
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary

上次更新時間 2020-25-11 於 03:04