High-Nuclearity Silver Thiolate Clusters Constructed with Phosphonates
Publication in refereed journal

香港中文大學研究人員

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摘要The n-butylphosphonate ligand has been employed to construct three new silver(I) thiolate compounds. Singlecrystal X-ray analysis revealed that complexes 1 and 2 are Ag-48 and Ag-51 coordination chain polymers, while 3 contains a discrete Ag-48 cluster, in which three different kinds of silver(I) thiolate cluster shells enclose three different phosphonate- functionalized silver(I) cluster cores, respectively. The structures of clusters in 1-3 feature three three-shell arrangements, S@Ag-12@(nBuPO(3))(9)@Ag36S23, S@Ag-11@(nBuPO(3))(7)-(MoO4)(2) @Ag40S27 and MoO4@Ag-12@(nBuPO(3))(8)S-6 @Ag36S24, respectively.
著者Xie YP, Jin JL, Lu X, Mak TCW
期刊名稱Angewandte Chemie International Edition
出版年份2015
月份12
日期7
卷號54
期次50
出版社WILEY-V C H VERLAG GMBH
頁次15176 - 15180
國際標準期刊號1433-7851
電子國際標準期刊號1521-3773
語言英式英語
關鍵詞cage compounds; clusters; phosphonates; silver; thiolates
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary

上次更新時間 2020-25-11 於 03:00