Assembly of Organosilver (I) Networks with Multinuclear Supramolecular Synthons Containing All-carbon and Carbon-rich Anionic Ligands
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AbstractThis review summarizes recent advances conducted by our group on related silver complexes of (a) all-carbon ligands C-6(2-) and C-8(2-), (b) 1, 5-hexadiyne-1, 6-diide C6H42-, (c) ethynediide C-2(2-) and ethynide R-C-2(-) assembled with phosphonic acids, (d) aryl, alicyclic and heteroaromatic ethynides, and (e) ethynides that are stabilized by different types of silver center dot center dot center dot carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.
All Author(s) ListHau SSK, Hu T, Taw DYS, Mak TCW
Journal nameGao Deng Xue Xiao Hua Xue Xue Bao ==
Volume Number36
Issue Number11
Pages2115 - 2133
LanguagesEnglish-United Kingdom
KeywordsAll-carbon ligand; Argentophilicity; Carbon-rich ligand; Ethynide; Organosilver (I) network; Supramolecular synthon
Web of Science Subject CategoriesChemistry; Chemistry, Multidisciplinary

Last updated on 2020-18-10 at 01:40