A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)(2)Ir(mu-Ph(2)Ppy)(2)CdI2 [Ph(2)Ppy equals 2-(diphenylphosphino)pyridine]
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AbstractThe first binuclear (IrCdII)-Cd-I complex to be structurally characterised, I(CO)(2)Ir(mu-Ph(2)Ppy)(2)CdI2 [Ph(2)Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) Angstrom; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 mu s that presumably originates from a (MLCT)-M-3 excited state.
All Author(s) ListKuang SM, Xue F, Zhang ZZ, Xue WM, Che CM, Mak TCW
Journal nameJournal of the Chemical Society, Dalton Transactions (1972-1999)
Year1997
Month10
Day7
Issue Number19
PublisherROYAL SOC CHEMISTRY
Pages3409 - 3410
ISSN0300-9246
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear

Last updated on 2020-01-08 at 02:18