A dinuclear manganese(II) complex doubly bridged by skew-skew mu-carboxylato groups: Synthesis and X-ray structure of [{Mn(bpy)(2)(p-Me(2)N+C5H4NCH2CO2-)}(2)](ClO4)(4)
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AbstractIn the novel centrosymmetric dinuclear manganese(II) complex [{Mn(bpy)(2)(p-Me(2)N(+)C(5)H(4)NCH(2) CO2-)}(2)](ClO4)(4), the bridging betaine ligand functions in an abnormal non-planar skew-skew mode, with both Mn-II atoms lying on the same side of the mean plane of each bridging carboxylato group. The intramolecular metal-metal separation in the dinuclear cation agrees well with those in the range 4.64-4.79 Angstrom found for known doubly carboxylato-bridged manganese(II) complexes. Copyright (C) 1996 Elsevier Science Ltd
All Author(s) ListWei PR, Li Q, Leung WP, Mak TCW
Journal namePolyhedron
Year1997
Month1
Day1
Volume Number16
Issue Number6
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Pages897 - 902
ISSN0277-5387
LanguagesEnglish-United Kingdom
Keywords4-dimethylaminopyridinioacetate; betaine; bridging ligand; carboxylate; dinuclear manganese(II) complex
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear; CHEMISTRY, INORGANIC & NUCLEAR; Crystallography; CRYSTALLOGRAPHY

Last updated on 2020-05-08 at 05:42