A cleavage of the S-C bond in 2-aminothiophenal: Synthesis and crystal structure of [Ag-11(mu(5)-S) (mu(4)-S(2)CNEt(2))(6) (mu(3)-S(2)CNEt(2))(3)]
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AbstractThe reaction of AgNO3, NaS(2)CNEt(2) and H(2)NPhSH in the presence of (Ph(3)P)(3)CuCl in MeOH gave a polynuclear silver cluster compound, [Ag-11(mu(5)-S)(mu(4)-S(2)CNEt(2))(6)(mu(3)-S(2)CNEt(2))(3)]. A cleavage of the S-C bond and release of S2- from 2-amino-thiophenal occurred in the reaction. The core of Ag11S consists of five layers: Ag, 3Ag, 3AgS, 3Ag and Ag. The average Ag-Ag and Ag-S-c (S-c for core sulfur atom) distances are 3.046 and 2.513 Angstrom, respectively. Copyright (C) 1996 Elsevier Science Ltd
All Author(s) ListSu WP, Hong MC, Jiang FL, Lu HQ, Zhou ZY, Wu DD, Mak TCW
Journal namePolyhedron
Volume Number15
Issue Number22
Pages4047 - 4051
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear; CHEMISTRY, INORGANIC & NUCLEAR; Crystallography; CRYSTALLOGRAPHY

Last updated on 2020-03-04 at 00:50