The synthesis, structure and reactivity of an imine-stabilized carboranylphosphorus(I) compound
Publication in refereed journal

香港中文大學研究人員

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摘要A new imine-stabilized carboranyl-phosphinidene has been synthesized and structurally characterized. DFT studies suggest that the imine moiety provides an electron pair to stabilize carboranyl-phosphinidene. On the other hand, the sterically demanding carboranyl ligand can prevent the dimerization, facilitating the formation of monomeric phosphinidene. These observations are supported by the reactivity studies. Such a monovalent phosphorous(I) compound can undergo reactions with Cu(OAc)(2), S, Se, (TMS)CHN2 and HCl to give various phosphorus(III) species. All compounds are fully characterized by NMR spectroscopy, elemental analyses as well as single-crystal X-ray analyses.
著者Chan TL, Xie ZW
期刊名稱Chemical Communications
出版年份2016
月份1
日期1
卷號52
期次45
出版社ROYAL SOC CHEMISTRY
頁次7280 - 7283
國際標準期刊號1359-7345
電子國際標準期刊號1364-548X
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary

上次更新時間 2021-13-04 於 23:21