A Polycyclic Aromatic Hydrocarbon Bearing an All-cis Tetrabenzo-[5.5.5.5]fenestrane (Fenestrindane) Core Merged with Two Hexa-peri-hexabenzocoronene Units
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AbstractThe successful merging of two multiply tert-butylated hexa-peri-hexabenzocoronene (HBC) units with all-cis-tetrabenzo[5.5.5.5]fenestrane (fenestrindane) at two opposite aromatic rings was described. Due to steric inhibition of the tert-butyl substituents near the merging region with the fenestrindane core, attempts to construct a highly warped but fully conjugated polycyclic aromatic hydrocarbon that contains two cycloheptatriene rings failed to materialize.
All Author(s) ListAn P, Chow HF, Kuck D
Journal nameSYNLETT
Year2016
Month5
Day1
Volume Number27
Issue Number8
PublisherGEORG THIEME VERLAG KG
Pages1255 - 1261
ISSN0936-5214
eISSN1437-2096
LanguagesEnglish-United Kingdom
Keywordsarenes; cross-coupling; cyclization; Diels-Alder reaction; fused-ring systems
Web of Science Subject CategoriesChemistry; Chemistry, Organic

Last updated on 2020-26-10 at 00:29