Reactivity Study of a Pyridyl-1-azaallylgermanium(I) Dimer: Synthesis of Heavier Ether and Ester Analogues of Germanium
Publication in refereed journal


Times Cited
Web of Science5WOS source URL (as at 19/01/2021) Click here for the latest count
Altmetrics Information
.

Other information
AbstractThe reactivity study of a pyridyl-1-azaallylgermanium(I) dimer LGe-GeL [1; L = N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)] with different stoichiometric ratios of elemental selenium and tellurium is described. The reactions of 1 with 1 equiv of selenium and tellurium afforded the first example's of heavier ether analogues of germanium, bis(germylene) selenide and telluride LGe(mu-E)GeL [E = Se (2) and Te (3)], respectively. Meanwhile, the reactions of 1 with 2 equiv of selenium and tellurium gave the heavier ester analogues LGe=E(mu-E)GeL [E = Se (4) and (5)]. All compounds have been characterized by X-ray crystallography and multinuclear NMR spectroscopy.
All Author(s) ListLeung WP, Chan YC, So CW, Mak TCW
Journal nameInorganic Chemistry
Year2016
Month4
Day4
Volume Number55
Issue Number7
PublisherAMER CHEMICAL SOC
Pages3553 - 3557
ISSN0020-1669
eISSN1520-510X
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear

Last updated on 2021-20-01 at 01:46