6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes
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Abstract6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C-60 and C-70 in toluene.
All Author(s) ListDeng CL, Xiong XD, Chik DTW, Cai ZW, Peng XS, Wong HNC
Journal nameChemistry - An Asian Journal
Year2015
Month11
Day1
Volume Number10
Issue Number11
PublisherWILEY-V C H VERLAG GMBH
Pages2342 - 2346
ISSN1861-4728
eISSN1861-471X
LanguagesEnglish-United Kingdom
Keywordsfullerenes; host-guest chemistry; macrocycles; synthesis; tetraphenylene
Web of Science Subject CategoriesChemistry; Chemistry, Multidisciplinary

Last updated on 2021-12-04 at 23:28