Tetrathio and Tetraseleno[8]circulenes: Synthesis, Structures, and Properties
Publication in refereed journal


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摘要Novel sulfur and selenium-bridged [8]circulenes were prepared from octabromotetraphenylene. Structures of these compounds were unambiguously confirmed by X-ray crystallographic analyses. Photophysical and electrochemical investigations of these [8]circulenes suggest their potential applications as electronic materials. The antiaromatic nature of tetrathio[8]circulene and tetraselenium[8]circulene was studied by computational methods, and the NICS computational results reveal that the central eight-membered ring has highly antiaromatic character.
著者Xiong XD, Deng CL, Minaev BF, Baryshnikov GV, Peng XS, Wong HNC
期刊名稱Chemistry - An Asian Journal
出版年份2015
月份4
日期1
卷號10
期次4
出版社WILEY-V C H VERLAG GMBH
頁次969 - 975
國際標準期刊號1861-4728
電子國際標準期刊號1861-471X
語言英式英語
關鍵詞[8]circulene; antiaromaticity; density functional theory calculation; electrochemistry; photophysics
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary

上次更新時間 2020-14-10 於 03:03