Cyanative alkene-aldehyde coupling: Ni(0)-NHC-Et2AlCN mediated chromanol synthesis with high cis-selectivity at room temperature
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摘要Described are several classes of Ni(0) mediated cyanative alkene-aldehyde coupling reactions, providing 6-membered cores, which complement existing cyclization technology in several respects. Et2AlCN was used as both a cyclization accelerator and CN source. The NHC ligand may have a positive effect in differentiating reductive elimination and syn-beta-hydride elimination.
著者Ho CY
期刊名稱Chemical Communications
出版年份2010
月份1
日期1
卷號46
期次3
出版社ROYAL SOC CHEMISTRY
頁次466 - 468
國際標準期刊號1359-7345
電子國際標準期刊號1364-548X
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary; CHEMISTRY, MULTIDISCIPLINARY

上次更新時間 2021-23-09 於 00:20