Unexpected photooxidation of H-bonded tetracene
Publication in refereed journal

香港中文大學研究人員

引用次數
替代計量分析
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其它資訊
摘要In our attempts of tuning the molecular packing of tetracene with H-bonding, we found that tetracenediamide was much more vulnerable to photooxidation than tetracene in crystals despite their similar sensitivity to photooxidation in solution. Unexpectedly photooxidation of tetracenediamide in solution and in crystals show different regioselectivities. To explain the regioselectivity, a mechanism involving H-bonding is proposed. This study indicates that molecular packing in solid state can play an important role in solid-gas reactions.
著者Liang ZX, Zhao W, Wang SL, Tang Q, Lam SC, Miao Q
期刊名稱Organic Letters
出版年份2008
月份5
日期15
卷號10
期次10
出版社AMER CHEMICAL SOC
頁次2007 - 2010
國際標準期刊號1523-7060
電子國際標準期刊號1523-7052
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Organic; CHEMISTRY, ORGANIC

上次更新時間 2021-23-02 於 00:44