Total synthesis of (+/-)-pallavicinin and (+/-)-neopallavicinin
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AbstractThrough a biomimetic pathway, (+/-)-pallavicinin and (+/-)-neopallavicinin were synthesized from (+/-)-Wieland-Miescher ketone via Grob fragmentation, intramolecular aldol cyclization, and intramolecular Michael reaction. The synthesis was stereocontrolled efficiently and followed the stereochemistry of the Wieland-Miescher ketone, and could provide opportunities for access to analogues of pallavicinin, neopallavicinin, and other related bioactive diterpenoids.
All Author(s) ListPeng XS, Wong HNC
Journal nameChemistry - An Asian Journal
Year2006
Month7
Day17
Volume Number1
Issue Number1-2
PublisherWILEY-V C H VERLAG GMBH
Pages111 - 120
ISSN1861-4728
eISSN1861-471X
LanguagesEnglish-United Kingdom
Keywordsaldol reaction, biomimetic synthesis, diterpenoids, labdanes, total synthesis
Web of Science Subject CategoriesChemistry; Chemistry, Multidisciplinary; CHEMISTRY, MULTIDISCIPLINARY

Last updated on 2021-10-05 at 23:46