Titanacarborane amide catalyzed transamination of guanidines
Publication in refereed journal

香港中文大學研究人員

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摘要This work describes a catalytic transamination of guanidines with a broad substrate scope of primary, secondary, heterocyclic, aliphatic, and aromatic amines, using 5-10 mol % of the half-sandwich titanacarborane amide [sigma:eta(1):eta(5)-(OCH(2))-(Me(2)NCH(2))C(2)B(9)H(9)]Ti(NMe(2)) as catalyst. This reaction tolerates common functional groups. The reaction mechanism is also proposed.
著者Shen H, Xie ZW
期刊名稱Organometallics
出版年份2008
月份6
日期23
卷號27
期次12
出版社American Chemical Society
頁次2685 - 2687
國際標準期刊號0276-7333
電子國際標準期刊號1520-6041
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Inorganic & Nuclear; CHEMISTRY, INORGANIC & NUCLEAR; Chemistry, Organic; CHEMISTRY, ORGANIC

上次更新時間 2021-15-09 於 01:19