Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)-o-Oligophenylenes
Publication in refereed journal

香港中文大學研究人員

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摘要All of the M and P isomers of optically pure oligophenylenes with 6, 8, 10, and 12 phenyl rings were synthesized and fully characterized. The Suzuki cross-coupling reaction has been revealed to be a viable strategy in the syntheses of tetraphenylene derivatives, which, together with the copper-mediated oxidative cross-coupling reaction, were employed in the quest for the oligophenylenes. X-ray diffraction analysis in combination with specific rotation and circular dichroism spectroscopy unambiguously identified the unique covalent double-helical frameworks of these oligophenylene molecules.
著者Chen JX, Han JW, Wong HNC
期刊名稱Organic Letters
出版年份2015
月份9
日期4
卷號17
期次17
出版社American Chemical Society
頁次4296 - 4299
國際標準期刊號1523-7060
電子國際標準期刊號1523-7052
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Organic

上次更新時間 2020-24-10 於 01:47