Sulphur-impregnated flow cathode to enable high-energy-density lithium flow batteries
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AbstractRedox flow batteries are promising technologies for large-scale electricity storage, but have been suffering from low energy density and low volumetric capacity. Here we report a flow cathode that exploits highly concentrated sulphur-impregnated carbon composite, to achieve a catholyte volumetric capacity 294 Ah l(-1) with long cycle life (>100 cycles), high columbic efficiency (>90%, 100 cycles) and high energy efficiency (>80%, 100 cycles). The demonstrated catholyte volumetric capacity is five times higher than the all-vanadium flow batteries (60 Ah l(-1)) and 3-6 times higher than the demonstrated lithium-polysulphide approaches (50-117 Ah l(-1)). Pseudo-in situ impedance and microscopy characterizations reveal superior electrochemical and morphological reversibility of the sulphur redox reactions. Our approach of exploiting sulphur-impregnated carbon composite in the flow cathode creates effective interfaces between the insulating sulphur and conductive carbon-percolating network and offers a promising direction to develop high-energy-density flow batteries.
All Author(s) ListChen HN, Zou QL, Liang ZJ, Liu H, Li Q, Lu YC
Journal nameNature Communications
Detailed descriptionI.F. = 12.124 (2016) I.F. = 13.096 (5 year)
Year2015
Month1
Day7
Volume Number6
PublisherNATURE PUBLISHING GROUP
Pages5877
ISSN2041-1723
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesMultidisciplinary Sciences; Science & Technology - Other Topics

Last updated on 2020-23-11 at 00:20