Revisiting zethrene: synthesis, reactivity and semiconductor properties
Publication in refereed journal

香港中文大學研究人員

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其它資訊
摘要Zethrene, a unique polycyclic aromatic hydrocarbon with formally fixed C-C double bonds, is predicted to have interesting properties and potential applications as an optical and electronic material. Here we report a novel synthesis of zethrene with improved yield, which presumably involves dinaphtho[10]-annulene as an unstable intermediate. With this convenient access to zethrene, we used zethrene as a p-type semiconductor in thin film transistors for the first time. It is found that Diels-Alder addition to the bay region of zethrene leads to new derivatives of benzo[pqr]naphtho[8,1,2-bcd]perylene, which behave as n-type organic semiconductors.
著者Shan L, Liang ZX, Xu XM, Tang Q, Miao Q
期刊名稱Chemical Science
出版年份2013
月份1
日期1
卷號4
期次8
出版社Royal Society of Chemistry: Chemical Science
頁次3294 - 3297
國際標準期刊號2041-6520
電子國際標準期刊號2041-6539
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary; CHEMISTRY, MULTIDISCIPLINARY

上次更新時間 2020-27-10 於 00:41