Systematic Investigation of Silver-Carbon Bonding in Coordination Frameworks with Aryl Ligands That Contain Ethynyl and Ethenyl Substituents
Publication in refereed journal


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摘要Single-crystal X-ray diffraction of a series of ten crystalline silver(I)trifluoroacetate complexes that contained designed ligands, each of which was composed of an aromatic system that was functionalized with terminal and internal ethynyl groups and a vinyl substituent, provided detailed information on the influence of ligand disposition and orientation, coordination preferences, and the co-existence of different types of silver(I)carbon bonding interactions (silverethynide, silverethynyl, silverethenyl, and silveraromatic) on the construction of coordination networks that were consolidated by argentophilic and weak inter/intramolecular interactions. The complex AgL106AgCF3CO2H2O MeOH (HL10=1-{[4-(prop-2-ynyloxy)-3-vinylphenyl]ethynyl}naphthalene) is the first reported example that exhibits all four kinds of silver(I)carbon bonding interactions in the solid state.
著者Hau SCK, Mak TCW
期刊名稱Chemistry - A European Journal
出版年份2013
月份4
日期1
卷號19
期次17
出版社Wiley: 12 months
頁次5387 - 5400
國際標準期刊號0947-6539
電子國際標準期刊號1521-3765
語言英式英語
關鍵詞coordination modes; crystal engineering; metalorganic frameworks; silver; X-ray diffraction
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary; CHEMISTRY, MULTIDISCIPLINARY

上次更新時間 2020-27-10 於 00:27