Insertion of Carboryne into Aromatic Rings: Formation of Cyclooctatetraenocarboranes
Publication in refereed journal

香港中文大學研究人員

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其它資訊
摘要1-lodo-2-lithiocarborane is an efficient precursor to carboryne. It can react with arenes to give different types of dearomatization products, [4+2] cycloaddition and/or cycloinsertion products, dependent upon the substituents on the aromatic rings. The formal cycloinsertion products, cyclooctatetraenocarboranes, is generated from the [2+2] cycloaddition intermediates followed by thermal [3,3] sigmatropic rearrangement. This novel dearomatization of arenes with carboryne also serves as an important method for the synthesis of cyclooctatetraenocarboranes.
著者Wang SR, Qiu ZZ, Xie ZW
期刊名稱Journal of the American Chemical Society
出版年份2010
月份7
日期28
卷號132
期次29
出版社AMER CHEMICAL SOC
頁次9988 - 9989
國際標準期刊號0002-7863
語言英式英語
Web of Science 學科類別Chemistry; Chemistry, Multidisciplinary; CHEMISTRY, MULTIDISCIPLINARY

上次更新時間 2021-25-02 於 00:48