Porous Nb4N5/rGO Nanocomposite for Ultrahigh-Energy-Density Lithium-Ion Hybrid Capacitor
Publication in refereed journal

香港中文大學研究人員
替代計量分析
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其它資訊
摘要To meet the increasing demands for high-performance energy storage devices, an advanced lithium-ion hybrid capacitor (LIHC) has been designed and fabricated, which delivers an ultrahigh energy density of 295.1 Wh kg(-1) and a power density of 41 250 W kg(-1) with superior cycling stability. The high-performance LIHC device is based on the uniform porous Nb4N5/rGO nanocomposite, which has an intimate interface between the firmly contacted Nb4N5 and rGO through the Nb(Nb4N5)-O(rGO)-C(rGO) bonds, significantly improving the electron transport kinetics. Moreover, the introduction of rGO nanosheets can prevent the Nb4N5 nanoparticles from agglomeration, not only resulting in a larger specific surface area to provide more active sites but also accommodating the strain during Li ion insertion/deinsertion. Therefore, the Nb4N5/rGO nanocomposite exhibits a higher reversible specific capacity and better rate and cycling performance than the Nb4N5 nanoparticle. In view of the scalable preparation and superior electrochemical characteristics, the Nb4N5/rGO nanocomposite would have great potential practical applications in the future energy storage devices.
著者Li SY, Wang T, Huang YP, Wei ZX, Li GC, Ng DHL, Lian JB, Qiu JX, Zhao Y, Zhang XY, Ma JM, Li HM
期刊名稱ACS Applied Materials and Interfaces
出版年份2019
月份7
日期10
卷號11
期次27
出版社American Chemical Society
頁次24114 - 24121
國際標準期刊號1944-8244
語言英式英語
關鍵詞Nb4N5/rGO nanocomposite, porous structure, ultrahigh energy/power densities, lithium-ion capacitor, energy storage
Web of Science 學科類別Nanoscience & Nanotechnology;Materials Science, Multidisciplinary;Science & Technology - Other Topics;Materials Science

上次更新時間 2021-16-01 於 23:04