1,2-Rearrangements of beta-nitrogen-substituted (porphyrinato)rhodium(III) ethyls
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Abstract(Porphyrinato)rhodium(III) ethyls containing beta-nitrogen substituents have been showed to undergo clean, thermal 1,2-rearrangements into the alpha-nitrogen-substituted rhodium ethyls. The rates and the equilibrium positions were found to be dependent on the electronic nature of the N substituents. Complexes 1a-3a were characterized by X-ray crystallography.
All Author(s) ListYeung SK, Chan KS
Journal nameOrganometallics
Year2005
Month5
Day23
Volume Number24
Issue Number11
PublisherAMER CHEMICAL SOC
Pages2561 - 2563
ISSN0276-7333
eISSN1520-6041
LanguagesEnglish-United Kingdom
Web of Science Subject CategoriesChemistry; Chemistry, Inorganic & Nuclear; CHEMISTRY, INORGANIC & NUCLEAR; Chemistry, Organic; CHEMISTRY, ORGANIC

Last updated on 2020-24-01 at 01:20